Evolution of the REE mineralogy in HP–LT metapelites of the Sebtide complex, Rif, Morocco: Monazite stability and geochronology     

Emilie Janots  Franois Negro  Fabrice Brunet  Bruno Goff  Martin Engi  Mohamed L. Bouybaoune 《Lithos》2006,87(3-4):214-234

REE mineralogy was characterized at the micrometer scale (using scanning electron microscopy) in the four tectono-metamorphic units of the Beni Mzala window, Sebtide Complex, Internal Rif, Morocco, which sample a HP-LT metamorphic gradient from subgreenschist to blueschist/eclogite facies. These tectonic units are composed of garnet-free metapelites (and associated synmetamorphic veins) from the same homogeneous aluminium-rich and calcium-poor protolith. In that context, mineralogical differences between units are assumed to result from contrasted pressure and temperature histories. Light REE-bearing Al-phosphates of the crandallite group with florencite-rich composition and variable goyazite content are the dominant LREE minerals in the lowest-grade units, Tizgarine (300 °C, 3 kbar as peak conditions) and Boquete de Anjera (350 °C, 10 kbar). In the latter unit, metamorphic florencite is associated with MREE-rich monazite. In the schist of the highest-grade units, Beni Mzala 2 (420–450 °C, 12 kbar) and Beni Mzala 1 (550 °C, 16 kbar), associations of allanite-rich epidote and synchisite (a LREE-fluorocarbonate) are found whereas florencite and monazite are no longer observed. At the wall of the quartz–kyanite veins, retrograde monazite-(Ce) with grain size of 20 to 50 μm is the only LREE-bearing mineral. Th–Pb and U–Pb SIMS data on some of these grains yield ages of 21.3 ± 1.7 Ma and 20.9 ± 2.1 Ma, respectively, consistent with previous K–Ar ages obtained on retrograde clay–mica mixtures in rocks from the same locality. The identification of a stability field for monazite in high-pressure aluminous metapelites with an upper thermal-limit below 450 °C as well as the derivation of meaningful U–Pb and Th–Pb SIMS ages demonstrates the monazite potential for dating HP-LT metapelites. However, since, under these conditions, monazite growth occurs below its admitted closure-temperature, these ages must be interpreted on the basis of monazite textural relationships.  相似文献   

球形氢键模型预测电解质溶液中的离子水合数          下载免费PDF全文

林联君  房春晖  房艳  秦绪锋 《盐湖研究》2006,14(3):43-48

建立了以球形氢键模型为基础的离子-水键长和配位水分子数之间的关系式,并利用该式对20种金属离子的水合数进行了预测,预测结果令人满意。  相似文献   

Hydrothermal Formation of Lath-Shaped Trioctahedral Smectite with High Crystallinity     

Hirohisa YAMADA Kenji TAMURA Shingo YOKOYAMA Yujiro WATANABE 《《地质学报》英文版》2006,80(2):290-295

Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at （a） 500℃ and 100 MPa for 1 and 11 days; and （b） 300℃ and 100 MPa for 7 days. The crystallinity and particle size of products were dependent on the chemical composition of the starting glass, synthetic temperature and duration of hydrothermal treatment. The high structural ordering and large dimensions of the products were confirmed from the sharpness of XRD peaks; and hydration behavior under controlled relative humidity. Transmission electron microscopy was also performed for the characterization of the particle size of product. Particle sizes vary from ca. 10 nm to a few pm by changing the chemical compositions of the starting materials. The product with the highest structural ordering and largest dimension was obtained from Nao.33（Mg1.83Al0.67）Si4O11 glass treated at 500℃ and 100 MPa for 1 day. The obtained results also confirmed the metastability and compositional dependency in the formation of highly crystalline trioctahedral smectite at hydrothermal conditions.  相似文献   

高温燃烧水解-离子选择电极法测定煤中氟     

雷翠琼 《云南地质》2007,26(3):360-364

高温燃烧水解-离子选择电极法测定煤中氟,具有灵敏度高、重现性好、干扰少等优点,在测量过程中多注意水解温度、水解时间、氧气通量及试液的pH调节等因素,可以得到更准确、可靠的测量结果。  相似文献   

连续自动再生化学抑制-离子色谱法测定石膏及其制品中的氟和氯     

钟坚海  郑瑞娟  陈金凤  陈章捷  张艳燕  林亚妹  刘明健 《岩矿测试》2015,34(3):330-334

测定石膏及其制品中的氟化物和氯化物,传统分析方法过程复杂,分析速度慢,准确度及灵敏度低。本文采用超声提取技术提取样品中的氟和氯,以Na2CO3-Na HCO3作为淋洗液,色谱柱分离后通过抑制器降低背景电导,用电导检测器进行检测。通过优化样品前处理和离子色谱分离条件,在测定范围内氟和氯的含量与峰面积呈良好的线性关系(相关系数0.9998),方法检测限为0.15 ng/m L(氟)和0.28 ng/m L(氯),加标回收率为95.0%~99.7%,精密度(RSD)均小于5%(n=8)。本方法采用超声提取技术,无需净化处理即可直接分析,半小时内完成前处理,且避免了目标分析物的损失。与离子选择电极法相比,检测限由μg/m L提升至ng/m L级别。  相似文献   

Improved thermodynamic calculations for concentrated mixed electrolyte systems including ion pairing (or the absence of it)     

Peter M. May   《Marine Chemistry》2006,99(1-4):62

Knowledge of the activity coefficients of solutes under temperature and pressure ranges of interest is generally required for calculations of the physicochemical properties of aqueous multicomponent electrolyte solutions such as seawater. Whilst these activity coefficients are well characterized for the predominant salts individually, fewer data are available for minor components under a sufficiently wide range of conditions and there are significant interactions between some of the chemical species involved which can substantially alter the required activity coefficients in mixtures.For these reasons, accurate thermodynamic predictions for seawater and other multi-electrolyte solutions in moderate or high concentration are more difficult than is often supposed. In particular, progress in this area has been slowed by uncertainty regarding the nature and extent of ion pairing in concentrated strong electrolyte solutions, a problem that has been debated for decades. Zdanovskii's rule, described originally almost a century ago but widely neglected, provides a fundamentally sound method for calculating the properties of mixed electrolyte solutions. Modelling developments are described, which accord with various types of experiment, from our laboratory and from the chemical literature. It has become clear that, when treated in an appropriate way based on solvent activity, linear mixing behaviour of strong electrolyte solutions can be considered the norm. This is an inevitable consequence, first recognized by Guggenheim, of the cancellation of ion pairing and other interactions as, conceptually, one ion replaces another. Stronger solute–solute interactions, described by equilibrium constants, can then easily be coupled in a thermodynamically consistent manner.  相似文献   

各种类型河蟹育苗用水的水质分析     

石俊艳  刘中  王晓光  丁茂昌  韩守谨 《海洋科学》2001,25(8):49-51

近几年,河蟹人工育苗已成为我省沿海种苗培育单位的重要产业 ,随着育苗规模的不断扩大及所带来的可观经济效益,各地又因地制宜发展起地下海水、浓缩海水的育苗生产,为搞清这几种育苗水体的水质特点 ,作者对这几种水体进行了分析检测,以服务于生产 ,为河蟹育苗的健康发展提供科学依据。１工作内容和方法１．１采样点自然海水采于营口市老边区三道沟和盘锦市二界沟;浓缩海水采于营口市青石岭育苗室及营口盐 　种型苗水ｐ ＣＤ营盐含量Ｔａｂ .1　ｐＨ ,ＣＯＤａｎｄｎｕｔｒｉｔｉｏｎｓａｌｔｏｆｅｖｅｒｙｋｉｎｄｏｆｂｒｅｅｄｉｎｇｗａ…  相似文献   

Gu's function scale of ion hydration force and charge size     

顾宏堪 《中国海洋湖沼学报》1997,15(2):186-191

ImODUonON'WaterVaporChemistry"isanewsdricediscovetalandestablishedfromtraceanaly-sisinGu'slab0rat0ry(Gu,l99l;Guetal.,l99l).Gu'sFunCtionshowrthatthetracetalionconcentfutionCinwatervaporhaspositivecondationt0the,Spedcelamnadriityconstant"lastionhationpotentialIz/ionvalenceZandnegativecondationtotheionvolumeVandcoordinationnUInberN(Gu,l994).Gu'sFunCti0nC=f[(IzwrVMofthebondparameterinwatervaporcheInistrycomepondstothepotentinlenergyfunctfonZ'd/rintheSbodingerEquahonofquantumchemistry.…  相似文献   

连续流动分析法测定污水中阴离子表面活性剂、总氮、总磷、挥发酚、氰化物、硫化物的方法及实例     

刘倩  刘光学 《地下水》2008,30(3):40-43

快速同时测定排污口样品中阴离子表面活性剂、总氮、总磷、挥发酚、氰化物、硫化物的分析方法。采用连续流动分析法,确定最佳实验方案。经多次试验验证,呈良好线性关系;质量控制样品测定值均在保证值范围内,样品回收率在95．2％～104％之间,RSD小于2％。  相似文献   

Determination of Free Nickel Ion Concentrations Using the Ion Exchange Technique: Application to Aqueous Mining and Municipal Effluents     

Yamini Gopalapillai  Ismail I. Fasfous  John D. Murimboh  Tahir Yapici  Parthasarathi Chakraborty  Chuni L. Chakrabarti 《Aquatic Geochemistry》2008,14(2):99-116

Free metal ion concentration is generally considered a useful indicator of a metal’s bioavailability and ecotoxicity to aquatic biota. This article reports the speciation of nickel in mining and municipal effluents from Sudbury (Ontario, Canada), and also in model solutions containing a fully characterized laurentian fulvic acid (LFA) at environmentally relevant concentrations. A column ion exchange technique (IET) using a cation exchange resin (Dowex 50W-X8) was applied to determine free nickel ion concentrations. In model solutions, reasonable correlation was found between the predictions of an equilibrium-based computer speciation code, Windermere Humic Aqueous Model (WHAM) VI, and the results obtained by IET at low nickel-to-fulvic acid ratios. However at higher mole ratios, the WHAM VI predicted higher free nickel ion concentrations than IET. Only three out of six effluent samples showed reasonable agreement between the IET and the WHAM VI results, indicating the need for further development of IET for application to effluent waters.  相似文献